Daily Practice Problems
NEET Chemistry
The d- and f-Block Elements
daily practice problem

Question 1:

Electronic configuration of a transition element X in +3 oxidation state is [Ar]3d5. What is its atomic number?

(a) 25

(b) 26

(c) 27

(d) 24 [Level: Easy]

 

Question 2:

The electronic configuration of Cu(II) is 3d9 whereas that of Cu(I) is 3d10. Which of the following is correct.

(a) Cu(II) is more stable

(b) Cu(II) is less stable

(c) Cu(I) and Cu(II) are equally stable

(d) Stability of Cu(I) and Cu(II) depends on nature of copper salts [Level: Moderate]

 

Question 3:

Metallic radii of some transition elements are given below. Which of these elements will have highest density?

Element                    Fe        Co       Ni        Cu

Metallic radii/pm   126     125     125     128

(a) Fe

(b) Ni

(c) Co

(d) Cu [Level: Moderate]

 

Question 4:

Generally, transition elements form coloured salts due to the presence of unpaired electrons. Which of the following compounds will be coloured in solid state?

(a) Ag2SO4

(b) CuF2

(c) ZnF2

(d) Cu2Cl2 [Level: Moderate]

 

Question 5:

On addition of small amount of KMnO4 to concentrated H2SO4 , a green oily compound is obtained which is highly explosive in nature. Identify the compound from the following.  

(a) Mn2O7

(b) MnO2

(c) MnSO4

(d) Mn2O3 [Level: Difficult]

 

Question 6:

The magnetic nature of elements depends on the presence of unpaired electrons. Identify the configuration of transition element, which shows highest magnetic moment.

(a) 3d7

(b) 3d5

(c) 3d8

(d) 3d2 [Level: Moderate]

 

Question 7:

Which of the following oxidation state is common for all lanthanoids?

(a) + 2

(b) + 3

(c) + 4

(d) + 5 [Level: Easy]

 

Question  8:

Which of the following reactions are disproportionation reactions?

 

 

 

(a) (i)

(b) (i), (ii) and (iii)

(c) (ii), (iii) and (iv)

(d) (i) and (iv) [Level: Moderate]

 

Question 9:

When KMnO4 solution is added to oxalic acid solution, the decolourisation is slow in the beginning but becomes instantaneous after some time because

(a) CO2 is formed as the product

(b) reaction is exothermic

(c) MnO4- catalyses the reaction

(d) Mn2+ acts as autocatalyst [Level: Difficult]

 

Question 10:

There are 14 elements in actinoid series. Which of the following elements does not belong to this series?

(a) U

(b) Np

(c) Tm

(d) Fm [Level: Easy]

 

Question 11:

KMnO4 acts as an oxidising agent in acidic medium. The number of moles of KMnO4 that will be needed to react with one mole of sulphide ions in acidic solution is

(a) 2/5

(b) 3/5

(c) 4/5

(d) 1/5 [Level: Difficult]

 

Question 12:

Which of the following oxides are amphoteric?

Mn2O7, CrO3 , Cr2O3, CrO, V2O5, V2O4

(a) V2O5 , Cr2O3

(b) Mn2O7, CrO3

(c) CrO, V2O5

(d) V2O5, V2O4 [Level: Moderate]

 

Question 13:

Gadolinium belongs to 4f series. Its atomic number is 64. Which of the following is the correct electronic configuration of gadolinium?

(a) [Xe]4f7 5d1 6s2

(b) [Xe]4f6 5d2 6s2

(c) [Xe]4f8 6d2

(d) [Xe]4f9 5s1 [Level: Easy]

 

Question 14:

Interstitial compounds are formed when small atoms are trapped inside the crystal lattice of metals. Which of the following is not the characteristic property of interstitial compounds?

(a) They have high melting points in comparison to pure metals

(b) They are very hard

(c) They retain metallic conductivity

(d) They are chemically very reactive [Level: Moderate]

 

Question 15:

The magnetic moment is associated with its spin angular momentum and orbital angular momentum. Spin only magnetic moment value of Cr3+ ion is

(a) 2.87 BM

(b) 3.87 BM

(c) 3.47 BM

(d) 3.57 BM [Level: Moderate]

 

Question 16:

KMnO4 acts as an oxidising agent in alkaline medium. When alkaline KMnO4 is treated with KI, iodide ion is oxidised to ..................

(a) I2

(b) IO

(c) IO3-

(d) IO4- [Level: Moderate]

 

Question 17:

Which of the following statements is not correct?

(a) Copper liberates hydrogen from acids

(b) In its higher oxidation states, manganese forms stable compounds with oxygen and fluorine

(c) Mn3+ and Co3+ are oxidising agents in aqueous solution

(d) Ti2+ and Cr2+ are reducing agents in aqueous solution [Level: Moderate]

 

Question 18:

In acidic medium, H2O2 changes Cr2O72– to CrO5 which has two (–O–O) bonds. Oxidation state of Cr in CrO5 is:-

(a) + 5

(b) + 3

(c) + 6

(d) – 10 [Level: Difficult]

 

Question 19:

The electronic configurations of Eu(Atomic No. 63), Gd(Atomic No. 64) and Tb (Atomic No. 65) are

(a) [Xe] 4f7 6s2, [Xe] 4f8 6s2 and [Xe] 4f8 5d1 6s2

(b) [Xe] 4f7 5d1 6s2, [Xe] 4f7 5d1 6s2 and [Xe] 4f9 6s2

(c) [Xe] 4f6 5d1 6s2, [Xe] 4f7 5d1 6s2 and [Xe] 4f8 5d1 6s2

(d) [Xe] 4f7 6s2, [Xe] 4f7 5d1 6s2 and [Xe] 4f9 6s2 [Level: Easy]

 

Question 20:

Name the gas that can readily decolourise acidified KMnO4 solution :

(a) SO2

(b) NO2

(c) P2O5

(d) CO2 [Level: Difficult]

**********

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All About Daily Practice Problems on NEET Chemistry The d- and f-Block Elements NCERT Chapter 8

Our Daily Practice Problems (DPPs) offer a diverse range of question types, including Multiple Choice Questions (MCQs) as well as short and long answer types. These questions are categorized into Easy, Moderate, and Difficult levels, allowing students to gradually progress and challenge themselves accordingly. Additionally, comprehensive solutions are provided for each question, available for download in PDF format - Download pdf solutions as well as Download pdf Questions. This approach fosters a holistic learning experience, catering to different learning styles, promoting self-assessment, and improving problem-solving skills. With our well-structured DPPs, students can excel in exams while gaining a deeper understanding of the subject matter. Hope you found the content on NEET Chemistry The d- and f-Block Elements NCERT Chapter 8 useful.

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